氯碘甲烷












































































氯碘甲烷



IUPAC名
Chloroiodomethane
识别

CAS号
593-71-5  ✓

PubChem
11644

ChemSpider
11154

SMILES


InChI


EINECS
209-804-8
性质

化学式
CH2ClI

摩尔质量
 176.38 g/mol g·mol⁻¹
外观
 无色液体

密度
 2.416 g/cm3 (20 °C)

2.422 g/cm3 (25 °C)

沸点
 108 - 109 °C

kH
 0.89 mol.kg-1.bar-1
危险性

警示术语
 R：R36/37/38

安全术语
 S：S23, S24/25

欧盟分类
 刺激性(Xi)

NFPA 704

NFPA 704.svg

1

1

0

 
若非注明，所有数据均出自一般条件（25 ℃，100 kPa）下。

氯碘甲烷是一种混合液体卤代甲烷，易溶于丙酮，甲苯，乙醚和醇类。它的折射率为1.5812 - 1.5832。


氯碘甲烷常用于环丙烷化反应（“Simmon-Smith反应”），曼尼希反应，胺甲基化反应，环氧化反应，开环化以及末端烯烃的加成反应。它常用于替代二碘甲烷试剂，这是由于其具有更高的收率和选择性。



参考文献





外部链接


  • Usage in organic synthesis



























  • 查

  • 论

  • 编


卤代甲烷

單鹵代

CH3F · CH3Cl · CH3Br · CH3I
雙鹵代

CH2F2 · CH2ClF · CH2BrF · CH2FI · CH2Cl2 · CH2BrCl · CH2ClI · CH2Br2 · CH2BrI · CH2I2
三卤代

CHF3 · CHClF2 · CHBrF2 · CHF2I · CHCl2F · CHBrClF* · CHClFI* · CHBr2F · CHBrFI* · CHFI2 · CHCl3 · CHBrCl2 · CHCl2I · CHBr2Cl · CHBrClI* · CHClI2 · CHBr3 · CHBr2I · CHBrI2 · CHI3
四卤代

CF4 · CClF3 · CBrF3 · CF3I · CCl2F2 · CF2BrCl · CClF2I · CBr2F2 · CBrF2I · CF2I2 · CCl3F · CBrCl2F · CCl2FI · CBr2ClF · CBrClFI* · CClFI2 · CBr3F · CBr2FI · CBrFI2 · CFI3 · CCl4 · CBrCl3 · CCl3I · CBr2Cl2 · CBrCl2I · CCl2I2 · CBr3Cl · CBr2ClI · CBrClI2 · CClI3 · CBr4 · CBr3I · CBr2I2 · CBrI3 · CI4
*：有手性的化合物



Comments

Post a Comment

Popular posts from this blog

Information security

Image
This article is part of a series on Information security Related security categories Internet security Cyberwarfare Computer security Mobile security Network security Threats Computer crime Vulnerability Eavesdropping Malware Spyware Ransomware Trojans Viruses Worms Rootkits Bootkits Keyloggers Screen scrapers Exploits Backdoors Logic bombs Payloads Denial of service Defenses Computer access control Application security Antivirus software Secure coding Secure by default Secure by design Secure operating systems Authentication Multi-factor authentication Authorization Data-centric security Encryption Firewall Intrusion detection system Mobile secure gateway Runtime application self-protection (RASP) v t e Information security , sometimes shortened to InfoSec , is the practice of preventing unauthorized access, use, disclosure, disruption, modification, inspection, recording or destruction of information. Th...
Read more

Volkswagen Group MQB platform

Image
The Volkswagen Group MQB platform is the company's strategy for shared modular design construction of its transverse, front-engine, front-wheel-drive layout (optional front-engine, four-wheel-drive layout) automobiles. Volkswagen spent roughly $60bn [1] developing this new platform and the cars employing it. The platform underpins a wide range of cars from the supermini class to the mid size SUV class. MQB allows Volkswagen to assemble any of its cars based on this platform across all of its MQB ready factories. This allows the Volkswagen group flexibility to shift production as needed between its different factories. Beginning in 2012, Volkswagen Group marketed the strategy under the code name MQB , which stands for Modularer Querbaukasten , translating from German to "Modular Transversal Toolkit" or "Modular Transverse Matrix". [2] [3] MQB is one strategy within VW's overall MB (Modularer Baukasten or modular matrix) program which also includes th...
Read more

Daniel Guggenheim

Image
Daniel Guggenheim 1925 photo Born ( 1856-07-09 ) July 9, 1856 Philadelphia, Pennsylvania Died September 28, 1930 (1930-09-28) (aged 74) Port Washington, New York Alma mater Peirce College Known for Battle for control of ASARCO Daniel Guggenheim Medal Spouse(s) Florence Shloss Children Meyer Robert Guggenheim Harry Guggenheim Gladys Eleanor Guggenheim Parent(s) Meyer Guggenheim Barbara Guggenheim Daniel Guggenheim, 1910 Daniel Guggenheim (July 9, 1856 – September 28, 1930) was an American mining magnate and philanthropist, and a son of Meyer and Barbara Guggenheim. Contents 1 Biography 2 Personal life 2.1 Aviation 2.2 Alaska 3 See also 4 References 5 Further reading 6 External links Biography Born and raised in Philadelphia, Daniel Guggenheim was sent to Switzerland as a young man to study the Swiss lace and embroidery business, and to serve as a buyer for his father's import firm. The...
Read more